Acids and Bases
- Acids and Bases, two classes of chemical compounds that display generally opposite characteristics.
- Acids taste sour, turn litmus (a pink dye derived from lichens) red, and often react with some metals to produce hydrogen gas.
- Bases taste bitter, turn litmus blue, and feel slippery.
- When aqueous (water) solutions of an acid and a base are combined, a neutralization reaction occurs.
- This reaction is characteristically very rapid and generally produces water and a salt.
- For example, sulfuric acid and sodium hydroxide, NaOH, yield water and sodium sulfate:
H2SO4 + 2NaOH=H2O + Na2SO4
o Modern understanding of acids and bases began with the discovery in 1834 by the English physicist Michael Faraday that acids, bases, and salts are electrolytes.
o That is, when they are dissolved in water, they produce a solution that contains charged particles, or ions, and can conduct an electric current Ionization. In 1884 the Swedish chemist Svante Arrhenius (and later Wilhelm Ostwald, a German chemist) proposed that an acid be defined as a hydrogen-containing compound that, when dissolved in water, produces a concentration of hydrogen ions, or protons, greater than that of pure water.
o Similarly, Arrhenius proposed that a base be defined as a substance that, when dissolved in water, produces an excess of hydroxyl ions, OH-. The neutralization reaction then becomes:
H+ + OH-=H2O
- A number of criticisms of the Arrhenius-Ostwald theory have been made.
- First, acids are restricted to hydrogen-containing species and bases to hydroxyl-containing species.
- Second, the theory applies to aqueous solutions exclusively, whereas many acid-base reactions are known to take place in the absence of water.
Read more...